TRIETHYL CITRATE

PRODUCT IDENTIFICATION

CAS NO. 77-93-0

TRIETHYL CITRATE

EINECS NO. 201-070-7
FORMULA HOC(CO2C2H5)(CH2CO2C2H5)2
MOL WT. 276.29
H.S. CODE  
TOXICITY Orl rat LD50: 5900 mg/kg
SYNONYMS Citric Acid, Triethyl Ester; TEC;
Ethyl citrate; Triaethylcitrat (German); Triethylester Kyseliny Citronove (Czech); 2-hydroxy-1,2,3-propanetricarboxylic Acid, Triethyl ester; Citroflex 2;
SMILES
 

CLASSIFICATION

 

PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL STATE

clear liquid

MELTING POINT -45 C
BOILING POINT 294 C
SPECIFIC GRAVITY 1.137
SOLUBILITY IN WATER

 

AUTOIGNITION  
pH  
VAPOR DENSITY 5.56
NFPA RATINGS Health: 0 Flammability: 1 Reactivity: 0

REFRACTIVE INDEX

 

FLASH POINT

155 C

STABILITY Stable under ordinary conditions

APPLICATIONS

Triethyl Citrate is used as a high boiling solvent and plasticizer for vinyl resins, cellulose acetates. It is a plasticizer permitted in the field of food additive, food contact material, medical, and pharmaceutical. It is used as a plasticiser and humectant for cigarette filters. It is widely used in cosmetics , lacquers and as a fragrance carrier.
SALES SPECIFICATION

APPEARANCE

clear liquid

ESTER CONTENT

99.0% max

WATER

0.25% max

ACID VALUE

0.2 max (mg KOH/g)

Specific Gravity 1.135 - 1.139
Refractive Index 1.440 - 1.442
Heavy Metals

10ppm max

COLOR, APHA

50 max

TRANSPORTATION
PACKING 225kgs in drum
HAZARD CLASS Not regulated
UN NO.  

GENERAL DESCRIPTION OF CITRIC ACID

Citric Acid (2-Hydroxy-1,2,3-propanetricarboxylic acid, in IUPAC naming) is a colourless crystalline organic compound belong to carboxylic acid family. It exists in all plants (especially in lemons and limes) and in many animal tissues and fluids. In biochemistry, it is involved in important metabolism of almost all living things; the Krebs cycle (also called citric acid cycle or tricarboxylic acid cycle), a part of the process by which animals convert food to energy. Citric acid works as a preservative ( or as an antioxidant) and cleaning agent in nature. It is commercially obtained by fermentation process of glucose with the aid of the mold Aspergillus niger and can be obtained synthetically from acetone or glycerol. It can be used as an sour taste enhancer in foods and soft drinks. The three carboxy groups lose protons in solution; resulting in the excellent pH control as a buffer in acidic solutions. It is used as a flavouring, stabilizing agent and acidulant (to control acidity) in food industry, in metal-cleaning compositions as it chelates metals. Citric acid is available in forms of anhydrous primarily and in monohydrate, the crystallized form from water. The hydrated form will be converted to the anhydrous form above 74 C. Citrate is a salt or ester of citric acid. Citrates are formed by replacing the acidic one, two, or all three of the carboxylic hydrogens in citric acid by metals or organic radicals to produce an extensive series of salts, esters, and mixed (solid) salts. Cirrates are used in food, cosmetics, pharmaceutical and medicine industries as well as in plastic industry; nutrient or food additives having functions of acidity regulator, sequestering and stabilizing agent, antioxidants synergist, firming agent; anticoagulant for stored whole blood and red cells and also for blood specimens as citrates chelate metal ions and saline cathartics, effervescent medicines; high boiling solvent, plasticizer and resin for food contact plastics.